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Pyrolysis Technology

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Basic principles of pyrolysis technology

Biomass pyrolysis refers to the process of thermally decomposing biomass through heating under anaerobic or oxygen-deficient conditions, resulting in the generation of solid, liquid, and gaseous products. This process involves complex physicochemical reactions, including drying, pyrolysis, carbonization, and other stages. During the pyrolysis process, the main components of biomass, such as cellulose, hemicellulose, and lignin, undergo cracking, condensation, and reforming reactions, generating a series of products with different physicochemical properties.

The basic mechanism of pyrolysis reaction can be summarized as follows: When biomass is heated to a certain temperature, water evaporation occurs first, followed by the fragmentation of macromolecular polymers in the biomass, producing small volatile substances. These volatile substances undergo further secondary reactions such as cracking, polymerization, and condensation in the gas phase, ultimately forming three main products: pyrolysis oil, pyrolysis gas, and pyrolysis char. The composition and properties of the pyrolysis products mainly depend on factors such as raw material characteristics, pyrolysis temperature, and residence time.

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Product characteristics

The products of biomass pyrolysis primarily consist of solid biochar, liquid bio-oil, and gaseous combustible gases. The distribution ratio of these three types of products is influenced by various factors, including pyrolysis type, operating temperature, heating rate, residence time, biomass type, and composition.

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Torrefaction

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Basic principles of torrefaction

Biomass torrefaction, also known as mild pyrolysis or low-temperature pyrolysis, is a mild thermal conversion technology specifically used for biomass pretreatment. It is a slow pyrolysis process carried out at atmospheric pressure and in an inert gas atmosphere within the temperature range of 200-300℃. Its main purpose is to improve the physicochemical properties of biomass and enhance its quality as a raw material for subsequent conversion or direct utilization.

The core mechanism of the torrefaction

The core mechanism of the torrefaction lies in the selective removal of water and some light volatile components from biomass, while retaining as much as possible the solid skeleton structure and most of the carbon elements. Within this temperature range, hemicellulose in biomass undergoes significant decomposition first, producing a large amount of water, carbon dioxide, and light oxygen-containing organics; cellulose and lignin are relatively stable, mainly undergoing structural rearrangement and partial cross-linking reactions. This differentiated decomposition behavior results in pyrolysis products with a lower oxygen-to-carbon ratio, higher energy density, and better hydrophobic properties.

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The positioning of Torrefaction pretreatment

The pretreatment and positioning of torrefaction make it a key technical link connecting biomass raw materials with high value-added applications. Untreated biomass raw materials generally have inherent defects such as high moisture content, low energy density, poor grindability, and strong moisture absorption, which severely limit their large-scale application in the industrial field. Through torrefaction pretreatment, the moisture content of biomass can be reduced from 30-50% to less than 5%, the volumetric energy density can be increased by 30-50%, the grinding energy consumption can be reduced by 70-90%, and at the same time, it acquires hydrophobic characteristics similar to coal, greatly expanding its application range and economic value.

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Temperature parameter

The temperature parameter of the biomass pyrolysis torrefaction process is the primary factor that distinguishes different technology types and determines the distribution of products. The operating temperature for torrefaction is typically within the range of 200-300℃. Within this temperature range, biomass undergoes partial thermal decomposition, mainly removing water and light volatile components, resulting in the highest yield of solid products (about 60-70%), while generating a small amount of gas and liquid products. 

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The characteristics of torrefied products are that they maintain the basic morphology of biomass, but their energy density is significantly increased, and their grindability and hydrophobicity are greatly improved, making them suitable as high-quality solid fuel or as excellent raw materials for subsequent pyrolysis.

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